Zeitschriftenartikel:
I. Mijatovic, G. Kickelbick, U. Schubert:
"Rearrangement of a Titanium Alkoxide Cluster upon Substitution of the Alkoxide Groups by Carboxylate Ligands - Synthesis of [Ti6O4(OEt)14(OOCPh)2] from [Ti7O4(OEt)20]";
European Journal of Inorganic Chemistry,
8
(2001),
S. 1933
- 1935.
Kurzfassung englisch:
Reaction of [Ti7O4(OEt)20] with benzoic acid results in the formation of the new cluster [Ti6O4(OEt)14(OOCPh)2] with concomitant rearrangement of the cluster structure. The molecular structure of the new cluster was determined by single-crystal X-ray diffraction and can be represented by the extended formula [Ti6(μ4-O)2(μ2-O)2(μ2-OEt)6(μ2-benzoate)2(μ1-OEt)8].
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.