Publications in Scientific Journals:
G. Kickelbick, T. Gallauner:
"A mixed copper(I)/copper(II) complex coordinated by a multidentate amidato ligand";
Acta Crystallographica Section E,
58
(2002),
3;
102
- 104.
English abstract:
The compound described in this paper, bis{1-[2-(N,N-dimethylamino)ethylamino]ethaniminato}dicopper(I,II) perchlorate, [Cu2(C6H13N3)2]ClO4, is the product of the reaction of [(H3CCN)4Cu]ClO4 with a substituted triazine ring system. The complex is a copper(I)/copper(II) compound in which each Cu atom has a square-planar coordination environment; the Cu-Cu distance is 2.4552 (14) Å.
The two Cu atoms are bridged by an amidate ligand, which was apparently formed in a ring-cleavage reaction of the triazine ring. Each cation has a twofold axis perpendicular to the Cu-amidate plane, bisecting the Cu-Cu bond.
Created from the Publication Database of the Vienna University of Technology.