Zeitschriftenartikel:
O. Metelkina, U. Schubert:
"Reaction of Metal Alkoxides with Lysine: Substitution of Alkoxide Ligands vs. Lactam Formation";
Monatshefte für Chemie,
134
(2003),
S. 1065
- 1069.
Kurzfassung englisch:
Reaction of Ti(OEt)4 with lysine results in the formation of Ti(OEt)3(lysinate), as previously reported. Contrary to that, Al(OsBu)3 only catalyzes the formation of 3-aminocaprolactam, and no substitution product was observed. The reaction of Zr(OBu)4 with lysine at room temperature produced both 3-aminocaprolactam and Zr(OBu)3(lysinate); the lysinate complex was not observed when the reaction was performed at elevated temperatures.
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.