[Zurück]

D. Sturmayr, U. Schubert:
"DFT Calculations on the Activation of Silanes by Platinum Complexes with Hemilabile P,N Ligands";
in: "Organosilicon Chemistry VI - From Molecules to Materials, Volume l", N. Auner, J. Weis (Hrg.); Wiley-VCH, Weinheim, 2005, ISBN: 3-527-31214-5, S. 399 - 403.

The primary steps in the reactions between hydrogeno- and chlorosilanes and platinum complexes (P_N)Pt(X)CH₃ (X = CH₃, H, Cl, SiH₃) with a hemilabile P_N ligand were investigated by DFT calculations, especially the stereochemical outcome of the initial oxidative addition reaction of the silane and the relaxation of the Pt(IV) intermediate by a reductive elimination.

http://aleph.ub.tuwien.ac.at/F?base=tuw01&func=find-c&ccl_term=AC05937093