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Publications in Scientific Journals:

N Abdel Ghani, Y. Issa, H. Mikosch, G. Bauer:
"Spectral Studies and Normal Coordinate Analysis of Some Symmetric 1,5-Diaryl-3-cyanoformazans";
Microchemical Journal, 61 (1999), 2; 85 - 93.



English abstract:
The 1,5-diaryl-3-cyanoformazans were prepared and subjected to IR, MS,1H NMR, and13C NMR spectral analysis. The results indicate the presence of a strong intramolecular hydrogen bond in the formazan molecule. Moreover, the two phenyl rings are equivalent and the CN and NH stretching vibrational modes are slightly affected with electron-withdrawing substituents and interact with the neighboring CC stretching mode. Thesyn, s-cisformazan form was supported by calculating the frequencies, normal coordinate analysis, force constant refinement, and group theory treatment. High quality of fitting between the experimental and calculated frequencies with all formazans has been achieved.


"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1006/mchj.1998.1680

Electronic version of the publication:
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6W6H-45CW465-1H-1&_cdi=6599&_user=103677&_orig=browse&_coverDate=02%2F28%2F1999&_sk=999389997&view=c&wchp=dGLbVlb-zSkWz&md5=0fc3e0565e63718491e138ad40da97d0&ie=/sdarticle.pdf


Created from the Publication Database of the Vienna University of Technology.