Vorträge und Posterpräsentationen (mit Tagungsband-Eintrag):
F. Hamza, G. Kickelbick:
"Binuclear Copper(II) Complexes as Building Blocks for the Synthesis of Inorganic-Organic Nanocomposites";
Vortrag: Junior Scientist Conference,
Vienna University of Technlogy;
19.04.2006
- 21.04.2006; in: "Junior Science Conference",
(2006),
ISBN: 3902463-05-8;
S. 115
- 116.
Kurzfassung englisch:
The formation and characterization of binuclear copper(II) complexes with polymerizable groups and their self-assembly characteristics was studied. The compounds Cu2(L1)4 .2CH3OH, Cu2(L2)4 .H2O, Cu2(L3)4.2DMF, Cu2(L1)4 .C4N2H4 with L1 = methacryate, L2 = vinyl acetate and L3 = adamantine carboxylate were synthesized and their molecular structure was characterized. Single crystal X-ray analysis reveals that all of these compounds are binuclear complexes in the typical paddle-wheel structure containing four bridging carboxylates and two axial ligands occupying the residual free coordination sites. These two positions allow exchange reactions with different molecules and can be used for the formation of inorganic-organic hybrid materials via coordinative interactions.
Elektronische Version der Publikation:
http://publik.tuwien.ac.at/files/pub-tch_6526.pdf
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.