[Zurück]

G. Kickelbick, D. Holzinger, D. Rutzinger, S. Ivanovici:
"Synthesis of Inorganic-Polymer Nanocomposites by Atom Transfer Radical Polymerization Using Initiators or Polymerizable Groups Attached to Transition Metals via Bidentate Ligands";
in: "Controlled/Living Radical Polymerization - From Synthesis to Materials", K. Matyjaszewski (Hrg.); herausgegeben von: ACS Division of Polymer Chemistry, Inc.; American Chemical Society, 2006, ISBN: 0-8412-3991-6, S. 269 - 278.

Metal alkoxides were fimctionalized by bidentate ligands based on β-diketones or acetoacetoxy-derivatives. The resulting complexes either carried Initiator or polymerizable groups for ATRP. In addition these compounds were used as precursors for the sol-gel process. Depending on the ftmctional group attached to the metal and the further processing of the derived compounds core-shell nanoparticles or crosslinked materials were obtained. Atom transfer radical polymerization proved that it is a valuable tool for the controlled formation of inorganic-organic hybrid materials.