Publications in Scientific Journals:
H. Fric, U. Schubert:
"Bis-Imide Derivatives of the Heterometallic Alkoxide Li4Ti4O4(OiPr)12";
Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences,
62
(2007),
487
- 490.
English abstract:
The imide derivatives Li4Ti4O2(NR)2(OiPr)12 (R=CH2C6H5, C6H11, C4H9) were obtained either by reaction of the amine adduct Ti2(OiPr)8(H2NR)2 with lithium di-iso-propylamide or butyllithium, or when the primary amine was first reacted with the base and then with Ti(OiPr)4. The structures of the imide derivatives are the same as that of Li4Ti4O4(OiPr)12 (=Li4Ti4(μ2-O)2(μ5-O)2(μ2-OiPr)4(μ3-OiPr)4(OiPr)4) with the two μ2-oxo groups replaced by two μ2-NR groups.
Keywords:
Titanium Alkoxide Derivatives; Lithium Alkoxide Derivatives; Imide Ligands
Created from the Publication Database of the Vienna University of Technology.