Zeitschriftenartikel:
J. Le Bideau, J. Gaveau, S. Bellayer, M.-A. Néouze, A. Vioux:
"Effect of confinement on ionic liquids dynamics in monolithic silica ionogels 1H NMR study";
Physical Chemistry Chemical Physics,
9
(2007),
S. 5419
- 5422.
Kurzfassung englisch:
1H MAS NMR and temperature-dependent relaxation time measurements were carried out for the first time on ionic liquids confined in monolithic silica matrices and enabled us to show that the ionic liquids´ dynamics experienced only a very small slowing-down. The confinement preserved the ionic liquids´ properties and, moreover, allowed liquid-like behaviour at temperature below the crystallisation temperature of genuine ionic liquid. This study highlights the interest of the ionogel approach to all-solid state devices with genuine ionic liquid properties.
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1039/b711539c
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.