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H. Liu, U. Schubert:
"Novel MOFs Materials Based On A Spherosilicate";
Poster: 3rd International Symposium "Advanced Micro- and Mesoporous Materials", Albena. Bulgaria; 2009-09-06 - 2009-09-09; in: "Advanced Micro- and Mesoporous Materials -Book of Abstracts", (2009), ISBN: 978-954-323-558-2; 189.

The construction of metal-organic frameworks (MOFs) with novel structures and topologies has attracted great interest from chemists in the past decade because of their potential applications in many fields such as material science, heterogeneous catalysis, non-linear optics, and gas-storage. For the preparation of MOFs, carboxylic linkers are often used. Cages are ideal building blocks for constructing organic-inorganic hybrid materials. Recently, we have reported an octacarboxyl functionalized spherosilicate (OCPDS), which is a versatile precursor for multiple applications. In this work, we will use the preparative methodology used for the synthesis of MOFs and explore what structures are obtained when OCPDS is employed in MOF-like reactions with metal ions or metal complexes.

Project Head Ulrich Schubert:
Hybridmaterialien auf der Basis eines neuen POSS-Derivats