Zeitschriftenartikel:
Van An Du, S. Baumann, G. Stipicic, U. Schubert:
"Cleavage of an Iron-Silicon Bond by Hexamethylphosphoric Triamide: Synthesis and Characterization of [SiCl3(HMPA)3]+[Fe(CO)4SiCl3]-";
Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences,
64b
(2009),
S. 1553
- 1557.
Kurzfassung englisch:
Addition of excess hexamethylphosphoric triamide (HMPA) to cis-Fe(CO)4(SiCl3)2 led to the exclusive formation of the new complex [SiCl3(HMPA)3]+[Fe(CO)4SiCl3]- by cleavage of an ironsilicon bond. A reaction mechanism is presented, based on density functional theory calculations.
Schlagworte:
Iron-Silicon Bond Cleavage - Anionic Metal Silyl Complex - Hexacoordinate Silicon - DFT Calculations
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.