[Zurück]

H. Grothe, P. Baloh, F. Weiss:
"Spectroscopy, microscopy and diffraction experiments devoted to ice clouds";
Hauptvortrag: ATCHEM Workshop 2010, Bayreuth, Germany (eingeladen); 24.02.2010 - 26.02.2010; in: "Workshop on Atmospheric Chemistry: kinetics and spectroscopy", J. Ofner, C. Zetzsch (Hrg.); (2010), S. 38.

Water ice and nitric acid hydrates exhibit very different particle morphologies, which have an enormous impact on its ability to scatter and reflect light. This has an effect not only on the detection of ice particles by satellite instruments or ground-based optical remote sensing but also interferes with earth´s radiation balance. Since most morphological investigations in the atmosphere are hampered due to an interference of the microscopic technique to the ice particles, one is dependent on laboratory model experiments. In the past, a scanning electron microscope required a sufficient vacuum in the sample chamber in order to prevent a diversion of the electron beam. Modern environmental electron microscopy uses an imaging gas (water or nitrogen), which connects different advantages and prevents several handicaps. Firstly, the imaging gas works as secondary-emission multiplier. Secondly, the gas discharges the sample surface regularly and makes insulators accessible to SEM. Thirdly, a mixture of water and nitrogen prevents dehydration of the sample. Here, we present ESEM pictures of nitric acid hydrates and water ices. These particles exhibit morphological changes during an annealing program which can be related to respective phase changes, which have been corroborated by X-ray diffraction and vibrational spectroscopy in former experiments. [1,2] Different techniques of sample preparation have been applied, which range from gas phase deposition, to quenching techniques and oil-matrix isolation of frozen droplets. Beside the assignment of ice and hydrate particles and the evaluation of their impact on the spectroscopic data, we could also identify phase separations into hydrates and ice or impurities. This is an interesting result since it gives an idea of the topology of frozen atmospheric particles, which comprise a mixture of different organic and inorganic substances.[3]

[1] H. Grothe, H. Tizek and I. K. Ortega "Metastable Nitric Acid Hydrates - Possible Constituents of Polar Stratospheric Clouds?" Faraday Discussion 2008, 137, 223-234.
[2] H. Grothe, H. Tizek, D. Waller and D. J. Stokes "The crystallization kinetics and morphology of nitric acid trihydrate" Phys. Chem. Chem. Phys. 2006, 8, 2232-2239.
[3] H. Grothe "Interactive comment on "Inhibition of ice crystallisation in highly viscous aqueous organic acid droplets" by B. J. Murray"; Atmospheric Chemistry and Physics Discussion, 2008, 8, 3992-3995.

http://publik.tuwien.ac.at/files/PubDat_184882.pdf

Projektleitung Hinrich Grothe:
Der Einfluss von biologischen Strukturen auf die Eisnukleation

Projektleitung Hinrich Grothe:
Der Einfluss von biologischen Strukturen auf die Eisnukleation - eine experimentelle Studie zur Klimaforschung