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Zeitschriftenartikel:

G. Ghosh, S. Moi, W. Linert:
"Kinetics and Mechanism of the Interaction of DL-methionine with Di-μ- Hydroxobis(1,10-Phenanthroline)Dipalladium(II) Ion in Aqueous Solution";
Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 40 (2010), 4; S. 285 - 292.



Kurzfassung englisch:
The synthesis of Schiff bases N,N'-bis(4-dodecyloxy-benzylidene-N-propyl)-piperazine (2) and N,N'-bis-[4-(4'-octyloxy-benzoic)-ester-benzylidene-N-propyl]-piperazine (6) in a multistep process is reported. The intermediates as well as the products were characterized by elemental analysis, melting point and IR, 1H and 13C-NMR spectroscopy. The complex formation of these Schiff bases with copper(II) perchlorate resulted in disruption of the imino bond and yielded N,N'-bis(3-aminopropyl)piperazineperchloratocopper(II) perchlorate, Cu(L)(ClO4)2, where L stands for N,N'-bis(3-aminopropyl-)piperazine. The nature of the complex is established by elemental analyses, IR and Raman spectroscopy and its structure by X-ray diffraction measurements. The mesomorphic ordering of the ligands have been checked.

Schlagworte:
copper(II) complex; perchlorat complex; Schiff base; spectral properties


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1080/15533171003766725


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.