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Zeitschriftenartikel:

M. Bendová, M. Puchberger, S. Pabisch, H. Peterlik, U. Schubert:
"Studies on the Formation of CdS Nanoparticles from Solutions of (NMe4)4[Cd10S4(SPh)16]";
European Journal of Inorganic Chemistry, 2010 (2010), 15; S. 2266 - 2275.



Kurzfassung englisch:
The stepwise cluster growth, and formation of CdS nanoparticles from solutions of (NMe4)4[Cd10S4(SPh)16] in dimethyl sulfoxide (DMSO), dimethylformamide (DMF) and acetonitrile was investigated. Cluster growth is fast in DMSO and DMF at room temperature, and slow in acetonitrile at elevated temperatures. Larger sulfide clusters (initially Cd32, then Cd54) are initially formed, which upon further growth eventually give rise to CdS nanoparticles. Strong evidence was found that the byproduct formed during the reaction in DMSO is mononuclear [Cd(SPh)x(DMSO)y](2-x)(x~3).


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/ejic.201000080



Zugeordnete Projekte:
Projektleitung Ulrich Schubert:
Polymere aus funktionellen Clustern


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.