Publications in Scientific Journals:
M. Bendová, M. Puchberger, S. Pabisch, H. Peterlik, U. Schubert:
"Studies on the Formation of CdS Nanoparticles from Solutions of (NMe4)4[Cd10S4(SPh)16]";
European Journal of Inorganic Chemistry,
2010
(2010),
15;
2266
- 2275.
English abstract:
The stepwise cluster growth, and formation of CdS nanoparticles from solutions of (NMe4)4[Cd10S4(SPh)16] in dimethyl sulfoxide (DMSO), dimethylformamide (DMF) and acetonitrile was investigated. Cluster growth is fast in DMSO and DMF at room temperature, and slow in acetonitrile at elevated temperatures. Larger sulfide clusters (initially Cd32, then Cd54) are initially formed, which upon further growth eventually give rise to CdS nanoparticles. Strong evidence was found that the byproduct formed during the reaction in DMSO is mononuclear [Cd(SPh)x(DMSO)y](2-x)(x~3).
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/ejic.201000080
Related Projects:
Project Head Ulrich Schubert:
Polymere aus funktionellen Clustern
Created from the Publication Database of the Vienna University of Technology.