Van An Du, G. Stipicic, M. Bendová, U. Schubert:
"Formation of the silylene-bridged complex Fe2(CO)62-SiCl2)3 from cis-Fe(CO)4(SiCl3)2: an experimental and computational study.";
Monatshefte für Chemie, 141 (2010), 6; S. 671 - 675.

Kurzfassung englisch:
Thermolysis of cis-Fe(CO)4(SiCl3)2 results in the formation of the novel compound Fe2(CO)62-SiCl2)3, which was characterized by single crystal X-ray diffraction. Density functional theory calculations were carried out to elucidate possible reaction steps leading to the formation of Fe2(CO)6(SiCl2)3, including CO dissociation and chlorine abstraction by a SiCl3 radical generated from homolytic Fe-Si bond cleavage involving a singlet-triplet intersystem crossing.

Metal silyl complexes - Homolytic bond cleavage - Bridging silylene ligand - DFT calculations

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