[Zurück]


Zeitschriftenartikel:

M. Bendová, M. Puchberger, U. Schubert:
"Characterization of Cd10S4(SPh)12 , the Thermal Decomposition Product of (NMe4)4[Cd10S4(SPh)16]: Synthesis of a Neutral Cd54 Sulfide Cluster and of a Polymeric Chain of Thiolate-Bridged Cd17 Sulfide Clusters";
European Journal of Inorganic Chemistry, 21 (2010), S. 3299 - 3306.



Kurzfassung englisch:
Contrary to claims in the literature that a cluster of the composition of Cd10S4(SPh)12 was formed by thermal treatment of (NMe4)4[Cd10S4(SPh)16], experimental evidence was gathered that the core structure of the cluster is not exclusively retained and other CdS species are also formed. When Cd10S4(SPh)12 was treated with PhSH/NEt3 only a part of the material was converted into (NHEt3)4[Cd10S4(SPh)16]. From solutions of Cd10S4(SPh)12 in strongly coordinating solvents the new neutral CdS clusters Cd54S28(SPh)52Lx (L = pyridine, DMSO or DMF) and [Cd17S4(SPh)26py] were crystallized. The latter forms polymeric chains of phenylthiolate-bridged Cd17 units.

Schlagworte:
Cadmium . Nanoparticles . Cluster compounds . S ligands . Rearrangement


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/ejic.201000454



Zugeordnete Projekte:
Projektleitung Ulrich Schubert:
Polymere aus funktionellen Clustern


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.