O. Costisor, M. Vlad, V. Sasca, I. Labadi, O. Carp, W. Linert:
"Synthesis, thermal behavior, and spectral properties of mixed-metal Cu(I)-VO(IV)-thiourea coordination polymers";
Monatshefte für Chemie, 142 (2011), 1; S. 39 - 44.

Kurzfassung englisch:
The heterometallic complexes [Cu(VO)2(CSN2H4)3Cl(OH)4]∑H2O, [Cu2(VO)2(CSN2H4)2(C2H3O2)2∑(OH)4], and [Cu2(VO)3(CSN2H4)4(C2H3O2)4(OH)4] were prepared and characterized in terms of their molecular electrical conductivity, electronic and IR spectra, and thermal behavior. A polymeric structure is proposed in which a thiourea ligand is bonded via a sulfur atom to the tetracoordinated copper(I) and via amino groups to the oxovanadium(IV) ion. The polymeric nature of the complexes is due to bridging via the OH, thiourea, and/or acetate moieties between oxovanadium(IV) coordination centers.

Copper, Vanadium, IR and VIS spectroscopy, Thermal behavior

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