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Publications in Scientific Journals:

S. Baumann, M. Puchberger, U. Schubert:
"Oximate-substituted zirconium alkoxides";
Dalton Transactions, 40 (2011), 6; 1401 - 1406.



English abstract:
The reaction of acetoxime, ethyl methyl ketoxime or cyclohexanone oxime with zirconium iso-propoxide gave dimeric alkoxo oximate derivatives [Zr(OiPr)(oximate)3]2. The oximate ligands are side-on coordinated and the alkoxo groups bridge the two metal centres. NMR spectroscopy revealed dynamic behaviour of the compounds in solution. When exposing a reaction mixture of zirconium butoxide and cyclohexanone oxime to ambient moisture, the oxo-alkoxo derivative Zr4O(OBu)8(ON C6H10)6 was obtained.


"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1039/c0dt00384k


Created from the Publication Database of the Vienna University of Technology.