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Publications in Scientific Journals:

Van An Du, A. Sidorenko, O. Bethge, S. Paschen, E. Bertagnolli, U. Schubert:
"Iron silicide nanoparticles in a SiC/C matrix from organometallic polymers: characterization and magnetic properties";
Journal of Materials Chemistry, 21 (2011), 33; 12232 - 12238.



English abstract:
Thermolysis of poly(ferrocenylsilane) at 1000 °C or poly[{(dimethylsilyl)ferrocenyl}diacety¬lene] at 850 °C resulted in ferromagnetic Fe3Si nanoparticles, well distributed in a SiC/C matrix. The average size of the formed nanoparticles, their size distribution and their agglomeration behaviour depend on the choice of polymer and the thermolysis conditions. The size-dependent magnetic properties of the nanoparticles were analyzed by SQUID measurements. The smallest Fe3Si nanoparticles (10-30 nm) are single magnetic domain particles with superparamagnetic behaviour.


"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1039/C1JM11099C


Created from the Publication Database of the Vienna University of Technology.