Zeitschriftenartikel:
M. Falge, V. Engel, S. Gräfe:
"Time-resolved photoelectron spectroscopy of coupled electron-nuclear motion";
Journal of Chemical Physics,
134
(2011),
S. 184307-1
- 184307-8.
Kurzfassung englisch:
We investigate pump-probe electron detachment spectroscopy in a model system which is ideally suited to study coupled electronic and nuclear wave-packet dynamics. Time-resolved photoelectron spectra are calculated within the adiabatic approximation and a discretization of the detachment continuum. These spectra are compared to those which derive from a non-Born-Oppenheimer description and a numerically exact treatment of the detachment process. In this way it is possible to identify the influence of non-adiabatic effects on the spectra in a systematic way and also to test commonly applied approximations.
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1063/1.3585692
Zugeordnete Projekte:
Projektleitung Stefanie Gräfe:
Beschreibung und Kontrolle von Elektronendynamik in starken Feldern
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.