[Zurück]

J. Yang, M. Puchberger, R. Qian, C. Maurer, U. Schubert:
"Zinc(II) Complexes with Dangling Functional Organic Groups";
European Journal of Inorganic Chemistry, 2012 (2012), 27; S. 4294 - 4300.

Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction with p-aminobenzoic acid, the compound [Zn₂(OOCCH₃)(OOC-C₆H₄-NH₂₃]_∞ was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.

Coordination polymers / Zinc / Carboxylate ligands / Schiff bases

http://dx.doi.org/10.1002/ejic.201200558