Publications in Scientific Journals:
J. Yang, M. Puchberger, R. Qian, C. Maurer, U. Schubert:
"Zinc(II) Complexes with Dangling Functional Organic Groups";
European Journal of Inorganic Chemistry,
2012
(2012),
27;
4294
- 4300.
English abstract:
Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction with p-aminobenzoic acid, the compound [Zn2(OOCCH3)(OOC-C6H4-NH23]∞ was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.
Keywords:
Coordination polymers / Zinc / Carboxylate ligands / Schiff bases
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/ejic.201200558
Created from the Publication Database of the Vienna University of Technology.