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Zeitschriftenartikel:

N. Dastbaravardeh, M. Schnürch, M.D. Mihovilovic:
"Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates";
Organic Letters, 14 (2012), 7; S. 1930 - 1933.



Kurzfassung englisch:
A Ru-catalyzed direct arylation of benzylic sp3 carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylboronates. Substitution of the pyridine directing group in the 3-position proved to be crucial in order to achieve high arylation yields. Furthermore, the pyridine directing group can be removed in high yields via a two-step protocol.


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1021/ol300627p

Elektronische Version der Publikation:
http://publik.tuwien.ac.at/files/PubDat_213637.pdf


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.