Publications in Scientific Journals:
N. Dastbaravardeh, M. Schnürch, M.D. Mihovilovic:
"Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates";
Organic Letters,
14
(2012),
7;
1930
- 1933.
English abstract:
A Ru-catalyzed direct arylation of benzylic sp3 carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylboronates. Substitution of the pyridine directing group in the 3-position proved to be crucial in order to achieve high arylation yields. Furthermore, the pyridine directing group can be removed in high yields via a two-step protocol.
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1021/ol300627p
Electronic version of the publication:
http://publik.tuwien.ac.at/files/PubDat_213637.pdf
Created from the Publication Database of the Vienna University of Technology.