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Zeitschriftenartikel:

Ch. Artner, A. Koyun, M. Czakler, U. Schubert:
"Mixed-Metal Oxo Clusters Structurally Derived from Ti6O4(OR)8(OOCR´)8";
European Journal of Inorganic Chemistry, 2014 (2014), 29; S. 5008 - 5014.



Kurzfassung englisch:
The mixed-metal oxo clusters FeTi5O4(OiPr)4(OMc)10 (OMc= methacrylate), Zn2Ti4O4(OiPr)2(OMc)10, Cd4Ti2O2(OAc)2-(OMc)10(HOiPr)2, [Ca2Ti4O4(OAc)2(OMc)10]n, and [Sr2Ti4O4-(OMc)12(HOMc)2]n were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti6O4(OR)8(OOCR´)8. The Ca and Sr derivatives consist of chains of condensed clusters.

Schlagworte:
Cluster compounds / Bimetallic compounds / Titanium / Chain structures / Carboxylate ligands


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/ejic.201402499


Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.