Publications in Scientific Journals:
Ch. Artner, M. Czakler, U. Schubert:
"New zirconium and zirconium-titanium oxo cluster types by expansion or metal substitution of the octahedral Zr6O8 structural motif";
Inorganica Chimica Acta,
432
(2015),
208
- 212.
English abstract:
The cluster core structures of Zr10O8(OBu)16(OOC-C6H4-CH2Cl)8 and Zr9O6(OBu)18(OOCCtriple bond; length of mdashCEt)6 are derived from that of known Zr6O4(OH)4(OOCR)12 clusters by expansion of the octahedral Zr6O8 core. The core structures of the heterobimetallic clusters Ti2Zr4O5(OH)2(OPr)(OOCCMe3)11 and Ti3Zr3O4(OH)3(OBu)3(OOCCMe3)10 can be regarded as hybrids between that of Zr6O4(OH)4(OOCR)12 and Ti6O6(OR)6(OOCR′)6.
Keywords:
Metal oxo clusters; Zirconium compounds; Titanium compounds; Carboxylate ligands; Bimetallic oxides
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1016/j.ica.2015.04.013
Related Projects:
Project Head Ulrich Schubert:
Anisotrope Funktionalisierung von Clustern
Created from the Publication Database of the Vienna University of Technology.