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Zeitschriftenartikel:

M. Czakler, Ch. Artner, U. Schubert:
"Influence of the Ti(OiPr)4: methacrylic acid ratio on the formed oxo/alkoxo clusters";
Monatshefte für Chemie, 146 (2015), 6; S. 897 - 902.



Kurzfassung englisch:
When Ti(OiPr)4 was reacted with increasing proportions of methacrylic acid (McOH), the compounds Ti2(OiPr)6(OMc)2(iPrOH), Ti6O4(OiPr)8(OMc)8, Ti9O8(OiPr)4(OMc)16, and Ti8O8(OMc)16 were obtained in sequence. This allowed conclusions on the relative ratio of substitution and hydrolysis reactions, the latter being due to ester formation between the acid and cleaved alcohol. This ratio is also influenced by the reaction temperature, since Ti4O2(OiPr)6(OMc)6 was formed instead of Ti6O4(Oi-Pr)8(OMc)8 at lower temperature with the same precursorratio.

Schlagworte:
Titanium alkoxides; Methacrylate ligands; Structure analysis


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1007/s00706-015-1443-6



Zugeordnete Projekte:
Projektleitung Ulrich Schubert:
Anisotrope Funktionalisierung von Clustern


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.