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Zeitschriftenartikel:

M. Czakler, Ch. Artner, U. Schubert:
"Titanium oxo/alkoxo clusters with both phosphonate and methacrylate ligands";
Monatshefte für Chemie, 146 (2015), 8; S. 1249 - 1256.



Kurzfassung englisch:
The clusters Ti5O(OiPr)11(OMc)(O3PR)3 (OMc = methacrylate; R = Et, CH2CH2CH2Br) and Ti10(OiPr)16(OMc)4(O3PCH2CH=CH2)10 were obtained when Ti(OiPr)4 was reacted with the corresponding bis(trimethylsilyl) phosphonate and methacrylic acid. Oxo clusters of the composition Ti6O4(OiPr)10(OMc)2(O3PR)2, with a variety of groups R (Et, Ph, CH=CH2, CH2Ph, CH2CH=CH2, CH2CH2CH2Br, CH2CH2CN, CH2C(O)Me, CH2CH2OC(O)C(Me)=CH2), were formed instead, when a stoichiometric amount of water was added to the reaction mixture.

Schlagworte:
Titanium alkoxides; Methacrylate ligands; Phosphonate ligands; Structure analysis


"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1007/s00706-015-1444-5



Zugeordnete Projekte:
Projektleitung Ulrich Schubert:
Anisotrope Funktionalisierung von Clustern


Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.