Publications in Scientific Journals:
M. Czakler, Ch. Artner, U. Schubert:
"Titanium oxo/alkoxo clusters with both phosphonate and methacrylate ligands";
Monatshefte für Chemie,
146
(2015),
8;
1249
- 1256.
English abstract:
The clusters Ti5O(OiPr)11(OMc)(O3PR)3 (OMc = methacrylate; R = Et, CH2CH2CH2Br) and Ti10(OiPr)16(OMc)4(O3PCH2CH=CH2)10 were obtained when Ti(OiPr)4 was reacted with the corresponding bis(trimethylsilyl) phosphonate and methacrylic acid. Oxo clusters of the composition Ti6O4(OiPr)10(OMc)2(O3PR)2, with a variety of groups R (Et, Ph, CH=CH2, CH2Ph, CH2CH=CH2, CH2CH2CH2Br, CH2CH2CN, CH2C(O)Me, CH2CH2OC(O)C(Me)=CH2), were formed instead, when a stoichiometric amount of water was added to the reaction mixture.
Keywords:
Titanium alkoxides; Methacrylate ligands; Phosphonate ligands; Structure analysis
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1007/s00706-015-1444-5
Related Projects:
Project Head Ulrich Schubert:
Anisotrope Funktionalisierung von Clustern
Created from the Publication Database of the Vienna University of Technology.