Publications in Scientific Journals:
J. Svoboda, Y.V. Shan, F.D. Fischer:
"A new self-consistent model for thermodynamics of binary solutions";
The newly developed self-consistent model exploits the trapping concept and calculates the numbers of A-A, A-B and B-B bonds in A-B alloys in dependence of the bond-energy parameter. Consequently the self-consistent model improves the classical regular solution model utilizing the assumption of random distribution of solute atoms. Remarkable differences between both models are demonstrated. The self-consistent model may significantly reduce the number of fitting parameters in the CALPHAD approach as well as experimental efforts.
Thermodynamics; Analytical methods; CALPHAD; Phase diagram; Self-consistent model
"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
Created from the Publication Database of the Vienna University of Technology.