Zeitschriftenartikel:
P. Siraprapa, S. Khemmachat, D. Peerapan, K. Föttinger, G. Rupprechter, P. Kongkachuichay:
"Synthesis of copper-nickel/SBA-15 from rice husk ash catalyst for dimethyl carbonate production from methanol and carbon dioxide";
Journal of Industrial and Engineering Chemistry,
31
(2015),
S. 156
- 166.
Kurzfassung englisch:
The SBA-15 was synthesized via sol-gel process by using rice hush ash and tetraethyl orthosilicate as silica sources at a ratio of 50:50. Subsequently, Cu-Ni bimetals were loaded on the SBA-15 and were tested for the direct synthesis of dimethyl carbonate from CH3OH and CO2. FTIR showed that methanol reacted with pre-adsorbed carbon dioxide to form methoxy carbonate species that was the reaction intermediate. It was found that 0.5 g of catalyst with Cu and Ni bimetal loading of 5 wt% exhibited the highest activities. Moreover, the molybdenum modified catalyst showed greater beneficial effects on the stabilization of the catalyst.
Schlagworte:
Dimethyl carbonate; Methanol; Carbon dioxide; Mesoporous silica; SBA-15
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1016/j.jiec.2015.06.019
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.