Vorträge und Posterpräsentationen (mit Tagungsband-Eintrag):
C. Knoll, D. Müller, M. Seifried, G. Giester, M. Reissner, P. Weinberger:
"Rigidity in iron (II) tetrazole spin crossover chains";
Vortrag: 42nd International Conference on Coordination Chemistry (ICCC),
Brest (Frankreich);
03.07.2016
- 08.07.2016; in: "Programme Book",
(2016).
Kurzfassung englisch:
An important feature of SCO compounds for a technological application based on their spin switching behavior is cooperativity between the metal centers, enabling an abrupt spin transition. Therefore, different iron(II) spin crossover chains based on bridging tetrazole ligands were synthesized. Main objective is an improved cooperativity through an enhancement of the ligand rigidity. The influence of several weak coordinating anions and different solvents on the molecular arrangement, and therefore the switching behavior has been investigated. Quantum chemical calculations, as well as elaborated diffractive studies provided relevant insights into the solvents´ and anions´ influence on the spin transition.
Schlagworte:
spin crossover, iron(II), tetrazoles
Elektronische Version der Publikation:
https://iccc2016.sciencesconf.org/resource/page/id/38
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.