[Zurück]

H. Lasfargues, T. Glechner, C.M. Koller, V. Paneta, D. Primetzhofer, S. Kolozsvári, D. Holec, H. Riedl, P.H. Mayrhofer:
"Non-reactively sputtered ultra-high temperature Hf-C and Ta-C coatings";
Surface & Coatings Technology, 309 (2017), S. 436 - 444.

Transition metal carbides are known for their exceptional thermal stability and mechanical properties, notably governed by the carbon content and the prevalent vacancies on the non-metallic sublattice. However, when using reactive deposition techniques, the formation of amorphous C-containing phases is often observed. Here, we show that non-reactive magnetron sputtering of HfC0.89 or TaC0.97 targets lead to fully crystalline coatings. Their C content depends on the target-to-substrate alignment and globally increases from HfC0.66 to HfC0.76 and from TaC0.69 to TaC0.75 with increasing bias potential from floating to − 100 V, respectively, when using a substrate temperature Tsub of 500 °C. Increasing Tsub to 700 °C leads to variations from TaC0.71 to TaC0.81. All HfCy films are single-phase face-centered cubic, whereas the TaCy films also contain small fractions of the hexagonal Ta2C phase. The highest hardness and indentation modulus among all coatings studied is obtained for TaC0.75 with H = 41.9 ± 0.3 GPa and E = 466.8 ± 15 GPa. Ab initio calculations predict an easy formation of vacancies on the C-sublattice, especially in the Ta-C system, and a temperature driven stabilization of defected structures at high temperatures, with fewer vacancies on the C sublattice for Hf-C than for Ta-C. The predicted phase stability is proven up to 2400 °C for both systems by annealing experiments in vacuum.

http://dx.doi.org/10.1016/j.surfcoat.2016.11.073