[Zurück]

N.T. Madhu, E. Knittl, K. Fekadu, K. Abuyea, E. Asefa, W. Linert:
"Thermal Decomposition Studies on Iron(III) Complexes of 1,2-Bis(imino-4´-antipyrinyl) ethane with Varying Counter Ions";
Journal of Chemistry and Applied Chemical Engineering, 1 (2017), 1; S. 1 - 4.

Phenomenological and mechanistic characteristics of the thermal
decomposition of perchlorate, nitrate, thiocyanate, chloride and
bromide iron(III) complexes with the Schiff base 1,2-bis(imino-4´-
antipyrinyl)ethane (GA) were studied by thermo gravimetric and
derivative thermo gravimetric analyses. It was observed that the
counter anions may have a major effect on the thermal stability of
the present complexes.The decomposition reaction mechanism is
in accordance with a `random nucleation with one nucleus on each
particle, i.e. the Mampel model´.

Iron(III) complexes; 1,2-Bis(imino-4´-antipyrinyl)ethane; Thermal decomposition; Mechanistic aspects

http://publik.tuwien.ac.at/files/publik_261365.pdf