[Zurück]

G. Pototschnig, N. Maulide, M. Schnürch:
"Direct Functionalization of C@H Bonds by Iron, Nickel, and Cobalt Catalysis";
Chemistry - A European Journal, 23 (2017), S. 9206 - 9232.

Non-precious-metal-catalyzed reactions are of increasing
importance in chemistry due to the outstanding
ecological and economic properties of these metals. In the
subfield of metal-catalyzed direct C@H functionalization reactions,
recent years have shown an increasing number of
publications dedicated to this topic. Nickel, cobalt, and last
but not least iron, have started to enter a field which was
long dominated by precious metals such as palladium, rhodium,
ruthenium, and iridium. The present review article
summarizes the development of iron-, nickel-, and cobaltcatalyzed
C@H functionalization reactions until the end of
2016, and discusses the scope and limitations of these transformations.

base metal catalysis;· C-H activation; · cobalt; · iron; · nickel

http://dx.doi.org/10.1002/chem.201605657