T. Ashebr, W. Linert, N.T. Madhu:
"A comparative thermal decomposition kinetics on 1,2-bis (imino-4'-antipyrinyl)ethane and 4-N-(4'-antipyrylmethylidene) aminoantipyrine Cu(II) complexes with varying counter anions";
Oriental Journal of Physical Sciences, 3 (2018), 2; S. 108 - 115.

Kurzfassung englisch:
A comparative thermal decomposition kinetic studies of Cu(II) complexes of 1,2-bis(imino-4'-antipyrinyl)ethane (GA) and 4-N-(4'-antipyrylmethylidene)aminoantipyrine (AA) with a variety of counter anions viz. ClO4-, NO3-, Cl- and Br - has been evaluated by TG analysis. The kinetic parameters activation energy (E), pre-exponential factor (A) and entropy of activation (ΔS) were calculated by using Coats-Redfern equation. This study shows that the thermal decomposition kinetics has been controlled by the ligand field as well as the counter anions.

Antipyrine, Cu(II), Kinetics, Thermal decomposition

Erstellt aus der Publikationsdatenbank der Technischen Universitšt Wien.