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Publications in Scientific Journals:

M. Mitterbauer, P. Knaack, S. Naumov, M. Markovic, A. Ovsianikov, N. Moszner, R. Liska:
"Acylstannanes: Cleavable and Highly Reactive Photoinitiators for Radical Photopolymerization at Wavelengths above 500 nm with Excellent Photobleaching Behavior";
Angewandte Chemie - International Edition, 57 (2018), 37; 12146 - 12150.



English abstract:
Withinthis work, anovel acylstannane-based
photoinitiator (PI) is presented. Tetrakis(2,4,6-trimethylben-
zoyl)stannane (1)displays outstanding properties compared to
state-of-the-art acylgermane-based initiators.Most impor-
tantly,the initiator shows absorption up to 550 nm, which
allows higher penetration depths,especially in highly filled
photopolymers.Besides that, 1 shows extremely high photo-
initiating activity towards (meth)acrylic double bonds,aswell
as very fast photobleaching.Furthermore,unlike many orga-
notin compounds, 1 shows surprisingly low cytotoxicity.


"Official" electronic version of the publication (accessed through its Digital Object Identifier - DOI)
http://dx.doi.org/10.1002/anie.201804094

Electronic version of the publication:
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201804094


Created from the Publication Database of the Vienna University of Technology.