Vorträge und Posterpräsentationen (ohne Tagungsband-Eintrag):
D. Schönbauer, M. Schnürch:
"Toluene as benzylating reagent for C- and N-benzylation";
Vortrag: 4th COST CHAOS Working Group Meeting,
Alcala;
22.03.2018
- 23.03.2018.
Kurzfassung englisch:
The development of protocols towards the C- and N-benzylation under C(sp³) activation of toluene is discussed . Preliminary work on the activation towards the C-benzylated product under oxidative conditions is shown1.Through further optimization a protocol for N-benzylation with perfluoro-2-iodoprapane under nickel catalysis was also developed.2
1. H. J. Zhang, F. Su and T. B. Wen, J Org Chem, 2015, 80, 11322-11329.
2. Y. Aihara, M. Tobisu, Y. Fukumoto and N. Chatani, J Am Chem Soc, 2014, 136, 15509-15512.
Schlagworte:
C-H Activation, Benzylation, transition metals
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.