[Zurück]

P. Weinberger, D. Müller, C. Knoll, M. Seifried, F. Kapsamer, W. Zeni, G. Giester, M. Reissner:
"Systematic Studies on Structural and Electronic Influences on the Spin Transition properties of Fe(II) Spin-Crossover Compounds";
Vortrag: 7^th Asian Conference on Coordination Chemistry (ACCC7) 2019, Kuala Lumpur, Malaysia (eingeladen); 15.10.2019 - 18.10.2019; in: "Programme", Institut Kimia Malaysia (Hrg.); (2019), S. 38.

For a rational design of materials based on the molecular bistability exhibited by iron(II) spin-crossover compounds it is of utmost importance to derive a structure-property relationship. Currently, there is no general building principle to accomplish such a desired feature. Therefore, we focus our research on the extremely versatile ligand system of N1-substituted tetrazoles using homologous series of complexes to elucidate structural and electronic influences on the spin transition behavior of Fe(II) spin-crossover compounds. Several series of mononuclear as well as 1D-chain-type and 3D-network polynuclear complexes will be presented allowing for the development of synthetic strategies towards a rational design.

iron(II); spin-crossover; tetrazole; structure-property relationship

https://publik.tuwien.ac.at/files/publik_282033.pdf