Zeitschriftenartikel:
D. Schönbauer, C. Sambiagio, T. Noël, M. Schnürch:
"Photocatalytic deaminative benzylation and alkylation of tetrahydroisoquinolines with N-alkylpyrydinium salts";
Beilstein Journal of Organic Chemistry,
16
(2020),
S. 809
- 817.
Kurzfassung englisch:
A ruthenium-catalyzed photoredox coupling of substituted N-aryltetrahydroisoquinolines (THIQs) and different bench-stable pyridinium salts was successfully developed to give fast access to 1-benzyl-THIQs. Furthermore, secondary alkyl and allyl groups were also successfully introduced via the same method. Additionally, the typically applied N-phenyl group in the THIQ substrate could be replaced by the cleavable p-methoxyphenyl (PMP) group and successful N-deprotection was demonstrated.
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.3762/bjoc.16.74
Elektronische Version der Publikation:
https://publik.tuwien.ac.at/files/publik_290946.pdf
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.