Zeitschriftenartikel:
N. Kratena, S. Pfeffer, V. Enev, G. Gmeiner, P. Gärtner:
"Synthesis of human long-term metabolites of dehydrochloromethyltestosterone and oxymesterone";
Steroids,
164
(2020),
108716.
Kurzfassung englisch:
We herein report the synthesis of the long-term metabolites "M4" (IUPAC: 4-chloro-17-hydroxymethyl-17-methyl-18-norandrosta-4,13-dien-3-ol) of dehydrochloromethyl-testosterone (DHCMT, Oral Turinabol) and "Oxy M9" (4-hydroxy-17β-hydroxymethyl-17α-methyl-18-norandrosta-4,13-dien-3-one) of oxymesterone (Oranabol). Both compounds were derived from a common synthetic route starting from dehydroepiandrosterone acetate. Four different stereoisomers were evaluated for metabolite M4. The previously assigned structure could be corrected regarding the C-3 and C-17 stereocenters.
Schlagworte:
steroid metabolites, DHCMT, oxymesterone
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1016/j.steroids.2020.108716
Elektronische Version der Publikation:
https://publik.tuwien.ac.at/files/publik_290992.pdf
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.