Zeitschriftenartikel:
Á. Pálvölgyi, M. Schnürch, K. Schröder:
"Carbamate-based P,O-ligands for asymmetric allylic alkylations";
Tetrahedron,
76
(2020),
51;
S. 1
- 8.
Kurzfassung englisch:
Herein we report the design and successful catalytic application of modified Trost-ligands in asymmetric allylic alkylation (AAA) reactions. A small set of carbamate-monophosphine P,O-ligands has been prepared in a straightforward two-step synthetic procedure. After optimization of the reaction conditions, high catalytic activities and excellent enantioselectivity up to >99% have been attained.
Schlagworte:
Chiral P,O-ligands, Tsuji-Trost reaction, Asymmetric synthesis, Palladium-catalyzed allylation
"Offizielle" elektronische Version der Publikation (entsprechend ihrem Digital Object Identifier - DOI)
http://dx.doi.org/10.1016/j.tet.2020.131246
Erstellt aus der Publikationsdatenbank der Technischen Universität Wien.