[Zurück]

M. Kury, K. Ehrmann, G. Harakaly, C. Gorsche, R. Liska:
"Low volatile monofunctional reactive diluents for radiation curable formulations";
Journal of Polymer Science Part A: Polymer Chemistry, 59 (2021), 19; S. 2154 - 2169.

In the last decades the importance of UV curable formulations has increased continuously. Their fast curing speed, solvent-free polymerization conditions, and the formation of hard and highly crosslinked photopolymer networks repre-sent major benefits. Commercial UV resins generally consist of multi-functional vinyl oligomers, photoinitiators, additives, and reactive diluents. Mono- and multi-functional reactive diluents serve as thinners to lower the overall resin vis-cosity and to improve processability. However, many monofunctional reactive diluents like isobornyl (meth)acrylate or benzyl (meth)acrylate exhibit high vola-tility, often already at room temperature. This causes adverse effects such as unpleasant odor, potential health risks, and changing resin composition during processing. A new group of monomers that show high potential for replacing traditional highly volatile reactive diluents are salicylate (meth)acrylates. In this work, salicylate-based thinners are synthesized, polymerized, and characterized with respect to their viscosity, volatility, thermal stability, photoreactivity, and thermomechanical properties of their homopolymers. Additionally, a first exam-ple of their diluting effect in a highly viscous difunctional polyester urethane methacrylate is demonstrated with 30 wt% of a cycloaliphatically and an aromat-ically substituted salicylate methacrylate. The polymers of the diluted resin exhibit similarly high glass transition temperatures of 110 and 126 􀀁C, which are in the range of the polymers of the undiluted resin.

low volatility, photopolymerization, radiation curing, reactive diluent, salicylate (meth) acrylate

http://dx.doi.org/10.1002/pol.20210171

https://onlinelibrary.wiley.com/doi/full/10.1002/pol.20210171