[Zurück]

F. Mirabella, M. Müllner, T. Touzalin, M. Riva, Z. Jakub, F. Kraushofer, M. Schmid, M. Koper, G. Parkinson, U. Diebold:
"Ni-modified Fe₃O₄(001) surface as a simple model system for understanding the oxygen evolution reaction";
Electrochimica Acta, 389 (2021), S. 13863801 - 13863811.

Electrochemical water splitting is an environmentally friendly technology to store renewable energy in
the form of chemical fuels. Among the earth-abundant first-row transition metal-based catalysts, mixed
Ni-Fe oxides have shown promising performance for effective and low-cost catalysis of the oxygen evolu-
tion reaction (OER) in alkaline media, but the synergistic roles of Fe and Ni cations in the OER mechanism
remain unclear. In this work, we report how addition of Ni changes the reactivity of a model iron oxide
catalyst, based on Ni deposited on and incorporated in a magnetite Fe 3 O 4 (001) single crystal, using a
combination of surface science techniques in ultra-high vacuum such as low energy electron diffraction
(LEED), x-ray photoelectron spectroscopy (XPS), low-energy ion scattering (LEIS), and scanning tunnel-
ing microscopy (STM), as well as atomic force microscopy (AFM) in air, and electrochemical methods
such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in alkaline media. A
significant improvement in the OER activity is observed when the top surface presents an iron fraction
among the cations in the range of 20-40%, which is in good agreement with what has been observed
for powder catalysts. Furthermore, a decrease in the OER overpotential is observed following surface ag-
ing in electrolyte for three days. At higher Ni load, AFM shows the growth of a new phase attributed
to an (oxy)-hydroxide phase which, according to CV measurements, does not seem to correlate with the
surface activity towards OER. EIS suggests that the OER precursor species observed on the clean and Ni-
modified surfaces are similar and Fe-centered, but form at lower overpotentials when the surface Fe:Ni
ratio is optimized. We propose that the well-defined Fe 3 O 4 (001) surface can serve as a model system
for understanding the OER mechanism and establishing the structure-reactivity relation on mixed Fe-Ni
oxides.

OER Fe-Ni oxides surface science electrochemistry water splitting

http://dx.doi.org/10.1016/j.electacta.2021.138638

https://publik.tuwien.ac.at/files/publik_297559.pdf